Extra Storage Capacity Enabled by Structural Defects in Pseudocapacitive NbN Monocrystals for High‐Energy Hybrid Supercapacitors
學年 110
學期 2
出版（發表）日期 2022-02-27
作品名稱 Extra Storage Capacity Enabled by Structural Defects in Pseudocapacitive NbN Monocrystals for High‐Energy Hybrid Supercapacitors
作品名稱（其他語言）
著者 Shaowen Zhou, Chao‐Lung Chiang, Jianqing Zhao, Guanjian Cheng, Tariq Bashir, Wanjian Yin, Junyi Yao, Shiqi Yang, Wanying Li, Jiaqi Wang, Xinyuan Wang, Yan‐Gu Lin, Lijun Gao
單位
出版者
著錄名稱、卷期、頁數 Advanced Functional Materials, 32(22), 2112592
摘要 Li-ion hybrid supercapacitors (LHSCs) are intensely studied due to their favorable power densities. However, combined higher energy density materials, particularly anodes, are desirably sought. Herein, a defect-dominating structure protocol is reported. Specifically, two visible structural defects, i.e., crystal vacancy and lattice distortion have been introduced in situ in ultrafine niobium nitride (NbN) monocrystals that are integrated into a carbon (C) framework. Highly reversible Li-ion storage capacities up to 540 mAh g−1 are demonstrated in such a NbN@C composite anode, together with excellent rate capability and cycling stability. An extra vacancy-induced capacity contribution of the defective NbN component is evidenced by first-principles density functional theory (DFT) simulations in contrast to perfect modeling. Coupling with an activated carbon (AC) cathode, the NbN@C//AC cell can deliver balanced energy and power densities of 53.8 Wh kg−1 and 7818 W kg−1 at 4 A g−1, and retain a desired energy density of 56.1 Wh kg−1 after 10 000 cycles at 1 A g−1. Findings from this study, particularly the demonstrated defects-induced extra capacity of pseudocapacitive materials, may inspire new structural material designs of LHSCs.
關鍵字
語言 en_US
ISSN
期刊性質 國內
收錄於 SCI SSCI Scopus
產學合作
通訊作者 Jianqing Zhao, Wanjian Yin, Yan‐Gu Lin, Lijun Gao
審稿制度 1
國別 USA
公開徵稿
出版型式 ,電子版
SDGS 可負擔的潔淨能源,產業創新與基礎設施