Butterfly-Shaped Dibenz[a,j]anthracenes: Synthesis and Photophysical Properties
學年 112
學期 1
出版（發表）日期 2023-08-25
作品名稱 Butterfly-Shaped Dibenz[a,j]anthracenes: Synthesis and Photophysical Properties
作品名稱（其他語言）
著者 Yan-Ying Wu, Yi-Lin Wu, Cheng-Lan Lin, Hung-Cheng Chen, Yao-Yuan Chuang, Chih-Hsien Chen, Chih-Ming Chou
單位
出版者
著錄名稱、卷期、頁數 Organic Letters 25(43), p.7763-7768
摘要 A strategy for the synthesis of dibenz[a,j]anthracenes (DBAs) from cyclohexa-2,5-diene-1-carboxylic acids is presented. Our approach involves sequential C–H olefination, cycloaddition, and decarboxylative aromatization. In the key step for DBA skeleton construction, the bis-C–H olefination products, 1,3-dienes, are utilized as substrates for [4 + 2] cycloaddition with benzyne. This concise synthetic route allows for regioselective ring formation and functional group introduction. The structural features and photophysical properties of the resulting DBA molecules are discussed.
關鍵字
語言 zh_TW
ISSN 1523-7060; 1523-7052
期刊性質 國外
收錄於 SCI EI
產學合作
通訊作者
審稿制度 是
國別 USA
公開徵稿
出版型式 ,電子版,紙本
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機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/125609 )