Facile synthesis of homoallylamines via α-regioselectivity in ultrasonic mediation and γ-adduct syn-stereoselective allylation with AlCl3-catalysis
學年 112
學期 2
出版（發表）日期 2024-06-08
作品名稱 Facile synthesis of homoallylamines via α-regioselectivity in ultrasonic mediation and γ-adduct syn-stereoselective allylation with AlCl3-catalysis
作品名稱（其他語言）
著者 Lee, Chuo-yu; Yen, Ya-chuan; Lee, Shih-yuan
單位
出版者
著錄名稱、卷期、頁數 Tetrahedron Letters 114,　155134
摘要 The allylation reaction of aldimines with allyl metal reagents is an important synthetic method for the preparation of homoallylamines. Therefore, we wish to report a highly regioselective and stereoselective allylation reaction under sonochemical Barbier-type reaction conditions. The high yields of regioselective α-adducts were achieved by reacting cinnamyl bromide, zinc, 1,2-dibromoethane, and aldimine in THF under sonochemical Barbier-type conditions. Highly regioselective and stereoselective allylation reactions were also achieved under Lewis acid-promoted Barbier-type reaction conditions.
關鍵字 Homoallylamine;Sonochemical Barbier-type reaction;Lewis acid
語言 en_US
ISSN 1873-3581
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 Adam Shih-Yuan
審稿制度 否
國別 TWN
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/125758 )