Chemically coupling SnO2 quantum dots and MXene for efficient CO2 electroreduction to formate and Zn–CO2 battery
學年 111
學期 1
出版（發表）日期 2022-09-13
作品名稱 Chemically coupling SnO2 quantum dots and MXene for efficient CO2 electroreduction to formate and Zn–CO2 battery
作品名稱（其他語言）
著者 Lili Han; Xianyun Peng; Hsiao-Tsu Wang; Pengfei Ou; Yuying Mi; Chih-Wen Pao; Jigang Zhou; Jian Wang; Xijun Liu; Way-Faung Pong; Jun Song; Zhang Lin; Jun Luo; Huolin L. Xin
單位
出版者
著錄名稱、卷期、頁數 Proceedings of the National Academy of Sciences 119(42), e2207326119
摘要 Electrochemical conversion of CO2 into formate is a promising strategy for mitigating the energy and environmental crisis, but simultaneously achieving high selectivity and activity of electrocatalysts remains challenging. Here, we report low-dimensional SnO2 quantum dots chemically coupled with ultrathin Ti3C2Tx MXene nanosheets (SnO2/MXene) that boost the CO2 conversion. The coupling structure is well visualized and verified by high-resolution electron tomography together with nanoscale scanning transmission X-ray microscopy and ptychography imaging. The catalyst achieves a large partial current density of −57.8 mA cm−2 and high Faradaic efficiency of 94% for formate formation. Additionally, the SnO2/MXene cathode shows excellent Zn–CO2 battery performance, with a maximum power density of 4.28 mW cm−2, an open-circuit voltage of 0.83 V, and superior rechargeability of 60 h. In situ X-ray absorption spectroscopy analysis and first-principles calculations reveal that this remarkable performance is attributed to the unique and stable structure of the SnO2/MXene, which can significantly reduce the reaction energy of CO2 hydrogenation to formate by increasing the surface coverage of adsorbed hydrogen.
關鍵字
語言 en_US
ISSN 0027-8424
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度 否
國別 USA
公開徵稿
出版型式 ,電子版
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機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/124308 )