Structural, opto-electrical, and band-edge properties of full-series multilayer SnS1-xSex (0≤x≤1) compounds with strong in-plane anisotropy
學年 111
學期 2
出版（發表）日期 2023-05-10
作品名稱 Structural, opto-electrical, and band-edge properties of full-series multilayer SnS1-xSex (0≤x≤1) compounds with strong in-plane anisotropy
作品名稱（其他語言）
著者 Hsueh, Hung-chung
單位
出版者
著錄名稱、卷期、頁數 Materials Today Advances 18
摘要 Two-dimensional (2D) semiconductors with black phosphorus (BP) structure have recently received considerable attention on the realization of polarized optoelectronic device, axial-dependent carrier transport, and asymmetric 2D electronic and energy device owing to the strong in-plane anisotropy presented in the van der Waal plane. In this work, multilayered SnS1-xSex chalcogenides of x ¼ 0, 0.2, 0.4, 0.5, 0.6, 0.8 and x ¼ 1 were grown by chemical vapor transport and then exfoliated on a SiO2/Si substrate for further optical characterization. Polarized micro-Raman experiment and theoretical Raman-mode calculation simultaneously demonstrate strong in-plane anisotropy with the maximum Raman intensity of the armchair (AM) chain vibration mode (Ag) shows mutual orthogonality to the zigzag (ZZ) chain-oriented mode (B1g) in the full-series multilayer SnS1-xSex (0  x  1). For the intermediate compositions between x ¼ 0.2 and x ¼ 0.8, a crucial physical mechanism as “symmetry breaking” has been proposed to account for the increased number of separated Ag and B1g modes with different energies as compared to those detected for the binary compounds of orthorhombic SnS and SnSe. For the band-edge anisotropy, the bandgap value of ZZ polarized direction is shown to be lower than that of the AM direction for each of the SnS1-xSex compounds evidenced by polarized-thermoreflectance experiments and first-principles calculations.
關鍵字 Phosphorene structure；Tin monochalcogenides；In-plane anisotropy；Polarized Raman spectroscopy；Band-edge structure
語言 en
ISSN 2590-0498
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 Hung-Chung Hsueh (薛宏中), Ching-Hwa Ho
審稿制度 是
國別 NLD
公開徵稿
出版型式 ,電子版,紙本
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