A [001]-oriented Hittorf`s phosphorus nanorods/polymeric carbon nitride heterostucture for boosting wide-spectrum-responsive photocatalytic hydrogen evolution from pure water
學年 108
學期 1
出版（發表）日期 2020-01-07
作品名稱 A [001]-oriented Hittorf`s phosphorus nanorods/polymeric carbon nitride heterostucture for boosting wide-spectrum-responsive photocatalytic hydrogen evolution from pure water
作品名稱（其他語言）
著者 Y. Zhu, C. Lv, Z. Yin, J. Ren, X. Yang, C. L. Dong, H. Liu, R. Cai, Y. C. Huang, W. Theis, S. Shen, D. Yang
單位
出版者
著錄名稱、卷期、頁數 Angewandte Chemie International Edition 59(2), p.878-883
摘要 Red phosphorus is a promising photocatalyst with wide visible‐light absorption up to 700 nm, but the fast charge recombination limits its photocatalytic hydrogen evolution reaction (HER) activity. Now, [001]‐oriented Hittorf's phosphorus (HP) nanorods were successfully grown on polymeric carbon nitride (PCN) by a chemical vapor deposition strategy. Compared with the bare PCN and HP, the optimized PCN@HP hybrid exhibited a significantly enhanced photocatalytic activity, with HER rates reaching 33.2 and 17.5 μmol h−1 from pure water under simulated solar light and visible light irradiation, respectively. It was theoretically and experimentally indicated that the strong electronic coupling between PCN and [001]‐oriented HP nanorods gave rise to the enhanced visible light absorption and the greatly accelerated photoinduced electron–hole separation and transfer, which benefited the photocatalytic HER performance.
關鍵字
語言 en_US
ISSN 1873-4766
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度 是
國別 DEU
公開徵稿
出版型式 ,電子版
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機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/120693 )

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