| Polynuclear Silver(I) Triazole Complexes: Ion Conduction and Nanowire Formation in the Mesophase | |
|---|---|
| 學年 | 104 |
| 學期 | 1 |
| 出版（發表）日期 | 2016-01-04 |
| 作品名稱 | Polynuclear Silver(I) Triazole Complexes: Ion Conduction and Nanowire Formation in the Mesophase |
| 作品名稱（其他語言） | |
| 著者 | Padi Y. S. Su; S. J. Hsu; Jing C. W. Tseng; Hsiu-Fu Hsu; Wen-Jwu Wang; Ivan J. B. Lin |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Chemistry 22(1), pp.323-330 |
| 摘要 | Examples of polynuclear metallomesogens are few. Herein,1,2,4-triazole ligands were used to prepare mono- and polynuclear silver(I) triazole metallomesogens. Besides showing an SmA phase in the mesophase, two interesting properties were observed. First, higher ion conductivity is always found for the polynuclear complexes than for the mononuclear complexes with the same anion, an observation contrary to the knowledge that migration of a monomeric cation should be faster than that of a polymeric cation. Second, thermolysis of the polynuclear silver(I) triazole complexes in the assembled mesophase yielded Ag nanowires, in an excellent demonstration of the assembled nature of the polynuclear silver(I) ions in the thermolysis process. |
| 關鍵字 | |
| 語言 | en |
| ISSN | |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Ivan J. B. Lin |
| 審稿制度 | 是 |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/109849 ) |
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