Sequential Electrochemical Oxidation of Alternating Benzene-Furan Oligomers | |
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學年 | 96 |
學期 | 1 |
出版(發表)日期 | 2007-10-01 |
作品名稱 | Sequential Electrochemical Oxidation of Alternating Benzene-Furan Oligomers |
作品名稱(其他語言) | |
著者 | Lin, C.-L. ; Wu, Y.-L.; Chen, C.-L.; Chou, C.-M.; Luh, T.-Y |
單位 | 淡江大學化學工程與材料工程學系 |
出版者 | American Chemical Society |
著錄名稱、卷期、頁數 | The Journal of Organic Chemistry 72(22), pp.8531-8534 |
摘要 | Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry. |
關鍵字 | |
語言 | en |
ISSN | 0022-3263 |
期刊性質 | 國外 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | USA |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/53660 ) |