| Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes | |
|---|---|
| 學年 | 99 |
| 學期 | 2 |
| 發表日期 | 2011-03-27 |
| 作品名稱 | Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes |
| 作品名稱（其他語言） | |
| 著者 | Hess, Jennifer L.; Hsieh, Chung-Hung; Darensbourg, Marcetta Y. |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 241st ACS National Meeting & Exposition |
| 會議地點 | Anaheim, CA, United States |
| 摘要 | Dinitrosyl iron complexes (DNICs) with S, N, or O coordination function as nitric oxide transfer agents in biol. systems.1,2 However, the few model complexes contg. N-donor ligands, specifically modeling histidine coordination, are extremely air sensitive and difficult to isolate; studies of their reactivity are sparce.3 We report a series of complexes utilizing N-heterocyclic carbenes (NHCs) as mimics of imidazole and histidine ligands. The {Fe(NO)2}10 EPR-silent complexes Fe(NO)2(CO)(IMe), Fe(NO)2(CO)(Ii-Pr), Fe(NO)2 |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20110327~20110331 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 241st ACS National Meeting & Exposition, INOR-39 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97606 ) |
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