| N2S2-nickel and iron nitrosyls as metallo ligands in synthetic analogs of the [FeFe]-H2ase enzyme active site | |
|---|---|
| 學年 | 101 |
| 學期 | 2 |
| 發表日期 | 2013-04-07 |
| 作品名稱 | N2S2-nickel and iron nitrosyls as metallo ligands in synthetic analogs of the [FeFe]-H2ase enzyme active site |
| 作品名稱（其他語言） | |
| 著者 | Darensbourg, Marcetta Y.; Hsieh, Chung-Hung; Ghosh, Pokhraj |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 245th ACS National Meeting & Exposition |
| 會議地點 | New Orleans, LA, United States |
| 摘要 | The unique diiron catalytic unit that exists in the active site of the [FeFe]-H2ase has obvious design features that have been exploited in the development of hydrogen processing catalysts utilizing earth abundant metals, nickel and iron. In particular, the pendant base feature within the bridging dithiolate has been adapted within a nickel-diphosphinocyclohexane-like ring providing a remarkable catalyst for H2 prodn.(Helm, Dubois, et al., Science, 2011 , 863-866) We will describe modifications of the (μ-S(CH2)3S)[Fe(CO)3]2 p.. |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20130407~20130411 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 245th ACS National Meeting & Exposition, INOR-636 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97597 ) |
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