Aza-bridged bis-1,10-phenanthroline acyclic derivatives: synthesis, structure, and regioselective alkylation
學年 98
學期 2
出版（發表）日期 2010-07-01
作品名稱 Aza-bridged bis-1,10-phenanthroline acyclic derivatives: synthesis, structure, and regioselective alkylation
作品名稱（其他語言）
著者 Kao, Hsien-Chang; Hsu, Chia-Jung; Hsu, Che-Wei; Lin, Chien-Ho; Wang, Wen-Jwu
單位 淡江大學化學學系
出版者 Kidlington: Pergamon
著錄名稱、卷期、頁數 Tetrahedron Letters 51(29), pp.3743–3747
摘要 A family of acyclic aza-bridged bis-1,10-phenanthroline compounds has been synthesized in a convenient way. The resulting compounds 2 and 2·HCl were fully characterized and their solid state structures and NMR spectroscopic properties were investigated to assess how the structural units affect the alkylation reactions. The results reveal the transoid structure for 2. The broadening NMR peak in 2 is shown to be due to an unusual intramolecular CH⋯N hydrogen bond. This unique conformation offers an efficient and regioselective method to prepare the amino-substituted bis-2,2′-1,10-phenanthroline derivatives and 1,10-phenanthrolino-N-alkylated compounds.
關鍵字 2-Chloro-1,10-phenanthroline; Amino-substituted-2,2’-bis-1,10-phenanthroline; 1,10-Phenanthrolino-N-alkylated compounds
語言 en
ISSN 0040-4039
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 Wang, Wen-Jwu
審稿制度 是
國別 GBR
公開徵稿
出版型式 紙本
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