Electron Transfer-Induced Hydrogenation of Anthracene Catalyzed by Gold and Silver Nanoparticles
學年 95
學期 2
出版（發表）日期 2007-07-01
作品名稱 Electron Transfer-Induced Hydrogenation of Anthracene Catalyzed by Gold and Silver Nanoparticles
作品名稱（其他語言）
著者 鄧金培; Shih, Wen-chen ; Mou, Chung-yuan
單位 淡江大學化學學系
出版者
著錄名稱、卷期、頁數 The Journal of Physical Chemistry C111, pp.9723
摘要 Anthracene hydrogenation in aqueous micellar solutions is catalyzed at room temperature by ionic-surfactant-protected gold and silver nanoparticles (NPs) with well-controlled particle sizes. When sodium borohydride was used as the hydrogen source in the presence of these NPs, the only product obtained in the reaction is 9,10-dihydroanthracene. During the course of the reaction, a blue shift in the surface plasmon resonance band of silver NPs was more prominent and lasted longer than that of gold NPs. The difference in the optical property of metal NPs was related to the charging of their surfaces, indicating that the metal NPs play a role as the nanoelectrode storing electrons from hydrides. At the same time, a remarkable size-dependence of catalytic activity was found for both gold and silver NPs. Mechanism about the electron transfer-relaying effects of metal NPs is proposed for the hydrogenation reaction.
關鍵字
語言 en
ISSN
期刊性質 國內
收錄於
產學合作
通訊作者
審稿制度 否
國別 TWN
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61584 )

機構典藏連結
SDGS 可負擔的潔淨能源