A facile and efficient synthesis of aryltriethoxysilanes via sonochemical Barbier-type reaction | |
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學年 | 95 |
學期 | 1 |
出版(發表)日期 | 2006-09-25 |
作品名稱 | A facile and efficient synthesis of aryltriethoxysilanes via sonochemical Barbier-type reaction |
作品名稱(其他語言) | |
著者 | 李世元; Lee, Adam Shih-yuan; Chang, Y. T.; Chu, S. F.; Tsao, K. W. |
單位 | 淡江大學化學學系 |
出版者 | Elsevier |
著錄名稱、卷期、頁數 | Tetrahedron Letters 47(39), pp.7085-7087 |
摘要 | A series of aryltriethoxysilanes was synthesized from the reaction mixture of aryl bromide, Mg powder, 1,2-dibromoethane and tetraethyl orthosilicate in THF under ultrasound. This sonochemical Barbier-type reaction provides a simple and efficient method for preparation of aryltriethoxysilanes. The Hiyama cross-coupling reaction of phenyltriethoxysilane with bromobenzene was investigated under different palladium catalysts and Pd(PhCN)2Cl2 was found to be the best choice. |
關鍵字 | |
語言 | en |
ISSN | 0040-4039 |
期刊性質 | 國外 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | GBR |
公開徵稿 | |
出版型式 | ,紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24934 ) |