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學年
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111 |
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學期
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2 |
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出版（發表）日期
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2023-05-03 |
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作品名稱
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Enhancing the Cycle-life of Initial-anode-free Lithium-metal Batteries by Pre-lithiation in Mn-based Li-rich Spinel Cathodes |
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作品名稱（其他語言）
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著者
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Leiyu Chen, Chao-Lung Chiang, Guifan Zeng, Yonglin Tang, Xiaohong Wu, Shiyuan Zhou, Baodan Zhang, Haitang Zhang, Yawen Yan, Tingting Liu, Hong-Gang Liao, Chuanwei Wang, Xiaoxiao Kuai, Yan-Gu Lin, Yu Qiao, Shi-Gang Sun |
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單位
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出版者
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著錄名稱、卷期、頁數
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Journal of Materials Chemistry A, 11, 11119-11125 |
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摘要
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Anode-free lithium metal batteries (AF-LMBs) are attracting growing attention due to the burgeoning pursuit of high energy density. However, the poor reversibility of lithium-ion plating/stripping on the Cu anode triggers multiple issues, including rapid capacity loss, active lithium loss, and short lifetime. Herein, a cathode pre-lithiation strategy combined with a fluorine-containing electrolyte is introduced to achieve long-lifetime AF-LMBs. Furthermore, contact pre-lithiation, a more advanced and convenient strategy, has been introduced to precisely control the lithiation degree by adjusting the contact time. It has been demonstrated that over-lithiated Li1.3Mn2O4 can deliver additional lithium ions during the charging process, thus exhibiting 94.4% capacity retention after 40 cycles. |
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關鍵字
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語言
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en |
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ISSN
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期刊性質
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國內 |
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收錄於
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SCI
SSCI
Scopus
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產學合作
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通訊作者
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Chuanwei Wang, Xiaoxiao Kuai, Yan-Gu Lin, Yu Qiao |
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審稿制度
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1 |
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國別
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GBR |
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公開徵稿
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出版型式
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,電子版 |