|
學年
|
110 |
|
學期
|
2 |
|
出版（發表）日期
|
2022-02-01 |
|
作品名稱
|
Electron Transfer dynamics and enhanced H2 production activity of Hydrangea-like BiOBr/Bi2S3-based Photocatalysts with Cu-complex As a Redox Mediator |
|
作品名稱（其他語言）
|
|
|
著者
|
Chi-Jung Chang, Chieh-Lin Huang, Yuan-Hsiang Yu, Ming-Chun Teng, Chao-Lung Chiang, Yan-Gu Lin |
|
單位
|
|
|
出版者
|
|
|
著錄名稱、卷期、頁數
|
Applied Surface Science, 576(A), 151870 |
|
摘要
|
A composite photocatalyst consisting of the BiOBr/Bi2S3 heterojunction and a Cu complex exhibited high H2 production activity through an efficient transport of charge by redox couple Cu(II)/Cu(I) of the complex. BiOBr was prepared by a microwave solvothermal method. Then, the BiOBr/Bi2S3 composite was prepared as a heterojunction photocatalyst by an ion-exchange process. The copper complex was then introduced as a co-catalyst or a redox mediator. The morphology, crystal properties, optical properties, surface chemistry, photocurrent response, and photocatalytic activity of these BiOBr/Bi2S3/copper complex composites were investigated. The formation of a BiOBr/Bi2S3 heterojunction and the introduction of Cu complex improved the performance of the photocatalysts. For the first time, operando X-ray absorption spectra were recorded in situ to unveil the local interaction at the reactant-photocatalyst interface toward the photocatalysis reaction of BiOBr/Bi2S3-Cu complex photocatalyst in the sacrificial agent solution (Na2S, Na2SO3). |
|
關鍵字
|
|
|
語言
|
en |
|
ISSN
|
|
|
期刊性質
|
國外 |
|
收錄於
|
SCI
SSCI
Scopus
|
|
產學合作
|
|
|
通訊作者
|
Chi-Jung Chang, Yan-Gu Lin |
|
審稿制度
|
1 |
|
國別
|
NLD |
|
公開徵稿
|
|
|
出版型式
|
,電子版 |