期刊論文
| 學年 | 112 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2024-06-08 |
| 作品名稱 | Facile synthesis of homoallylamines via α-regioselectivity in ultrasonic mediation and γ-adduct syn-stereoselective allylation with AlCl3-catalysis |
| 作品名稱（其他語言） | |
| 著者 | Lee, Chuo-yu; Yen, Ya-chuan; Lee, Shih-yuan |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Tetrahedron Letters 114, 155134 |
| 摘要 | The allylation reaction of aldimines with allyl metal reagents is an important synthetic method for the preparation of homoallylamines. Therefore, we wish to report a highly regioselective and stereoselective allylation reaction under sonochemical Barbier-type reaction conditions. The high yields of regioselective α-adducts were achieved by reacting cinnamyl bromide, zinc, 1,2-dibromoethane, and aldimine in THF under sonochemical Barbier-type conditions. Highly regioselective and stereoselective allylation reactions were also achieved under Lewis acid-promoted Barbier-type reaction conditions. |
| 關鍵字 | Homoallylamine;Sonochemical Barbier-type reaction;Lewis acid |
| 語言 | en_US |
| ISSN | 1873-3581 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Adam Shih-Yuan |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/125758 ) |