期刊論文
| 學年 | 109 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2021-02-01 |
| 作品名稱 | K8Cd21Pb7(P2O7)16 and KCd2P3O10: Two new phosphates featuring special structure configurations |
| 作品名稱（其他語言） | |
| 著者 | Na Li; Lu Qi; Lu Li; Zhongqi Jiang; Jihong Fu; Ming-Hsien Lee; Zhaohui Chen |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Journal of Solid State Chemistry v.294, 121834 |
| 摘要 | Two new phosphates, KCd2P3O10 and K8Cd21Pb7(P2O7)16, have been obtained using high-temperature molten method for the first time. They show three-dimensional (3D) framework structures composed of [Cd2P3O18]∞ layers for KCd2P3O10 and [Cd36P48O237]∞ corrugated layers for K8Cd21Pb7(P2O7)16. To the best of our knowledge, K8Cd21Pb7(P2O7)16 is the first Cd-based phosphate that is constructed by tremendous [Cd18P24O121]∞ anionic duplicate units, which contain intriguing multimember-rings (6-MR, 8-MR, 16-MR). In addition, K8Cd21Pb7(P2O7)16 contains coexistent Cd2O10 single rings and Cd3O12 twin rings, which have not been found in other Cd-based phosphates. The comparison of structures was carried out among all the relevant anhydrous Cd-based phosphates. Combining with theoretical analysis, the relationship between electronic structures and optical properties is further elaborated. |
| 關鍵字 | KCd2P3O10;K8Cd21Pb7(P2O7)16;[Cd18P24O121] skeleton;Structural comparison;Theoretical calculation |
| 語言 | en |
| ISSN | |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/121006 ) |