期刊論文
| 學年 | 109 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2020-10-09 |
| 作品名稱 | Black phosphorus composites with engineered interfaces for high-rate high-capacity lithium storage |
| 作品名稱（其他語言） | |
| 著者 | Hongchang Jin; Sen Xin, Chenghao Chuang; Wangda Li; Haiyun Wang; Jian Zhu; Huanyu Xie; Taiming Zhang; Yangyang Wan; Zhikai Qi; Wensheng Yan; Ying-Rui Lu; Ting-Shan Chan; Xiaojun Wu; John B. Goodenough; Hengxing Ji; Xiangfeng Duan |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Science 370(6513), p.192-197 |
| 摘要 | High-rate lithium (Li) ion batteries that can be charged in minutes and store enough energy for a 350-mile driving range are highly desired for all-electric vehicles. A high charging rate usually leads to sacrifices in capacity and cycling stability. We report use of black phosphorus (BP) as the active anode for high-rate, high-capacity Li storage. The formation of covalent bonds with graphitic carbon restrains edge reconstruction in layered BP particles to ensure open edges for fast Li+ entry; the coating of the covalently bonded BP-graphite particles with electrolyte-swollen polyaniline yields a stable solid– electrolyte interphase and inhibits the continuous growth of poorly conducting Li fluorides and carbonates to ensure efficient Li+ transport. The resultant composite anode demonstrates an excellent combination of capacity, rate, and cycling endurance. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | 0036-8075; 1095-9203 |
| 期刊性質 | 國外 |
| 收錄於 | SCI Scopus |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/120722 ) |