期刊論文
| 學年 | 108 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2020-03-06 |
| 作品名稱 | Reaction of small molecules O2, NO, CO, and the Naldini salt (PPh3)2MnBr2: Characterized by infrared spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction |
| 作品名稱（其他語言） | |
| 著者 | Bo‐Wei Huang; Minh‐Trung Nguyen; Chung‐Hung Hsieh |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Journal of the Chinese Chemical Society 67(3), p.370-375 |
| 摘要 | Addition of 2 equiv. of PPh3 to MnBr2 in tetrahydrofuran (THF) solution under N2 atmosphere results in the formation of Naldini salt (PPh3)2MnBr2 (1). Reaction of Complex 1 and O2, NO, and CO (with reducing agent) leads to Complex (OPPh3)2MnBr2 (2), (PPh3)2Mn(NO)Br2 (3), and (PPh3)2Mn(CO)3Br (4), respectively. Both Complexes 2 and 4 crystallize in the triclinic space group P‐1 with a = 9.94 Å, b = 10.11 Å, c = 10.53 Å; α = 65.42°, β = 63.16°, and γ = 89.22° of 2 and a = 10.23 Å, b = 12.26 Å, c = 14.44 Å and α = 97.03°, β = 104.34°, and γ = 106.33° of 4. The isoelectronic replacement of 3CO with 2NO yields the {Mn(NO)2}8 species (PPh3)2Mn(NO)2Br (5). The single crystal of 5 is in the monoclinic space group C2/c with a = 23.17 Å, b = 9.62 Å, c = 15.92 Å, and β = 114.91°. In the THF solution, Complex 5 serves as an NO source in the presence of NO trapping, Co(TPP), Co(TPP) = 5,10,15,20‐tetraphenyl‐21H,23H‐porphine cobalt(II). |
| 關鍵字 | bromide;carbon monoxide;manganese;Naldini salt;nitric oxide;oxygen;triphenyl phosphine |
| 語言 | en_US |
| ISSN | 2192-6549 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Chung-Hung H |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/120518 ) |