期刊論文
| 學年 | 108 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2019-11-21 |
| 作品名稱 | A Black Phosphorus–Graphite Composite Anode for Li‐/Na‐/K‐Ion Batteries |
| 作品名稱（其他語言） | |
| 著者 | Hongchang Jin; Haiyun Wang; Zhikai Qi; De-Shan Bin; Taiming Zhang; Yangyang Wan; Jiaye Chen; Chenghao Chuang; Ying-Rui Lu; Ting-Shan Chan; Huanxin Ju; An-Min Cao; Wensheng Yan; Xiaojun Wu; Hengxing Ji; Li-Jun Wan |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Angewandte Chemie 132(6), p.2338-2342 |
| 摘要 | Black phosphorus (BP) is a desirable anode material for alkali metal ion storage owing to its high electronic/ionic conductivity and theoretical capacity. In-depth understanding of the redox reactions between BP and the alkali metal ions is key to reveal the potential and limitations of BP, and thus to guide the design of BP-based composites for high-performance alkali metal ion batteries. Comparative studies of the electrochemical reactions of Li+, Na+, and K+ with BP were performed. Ex situ X-ray absorption near-edge spectroscopy combined with theoretical calculation reveal the lowest utilization of BP for K+ storage than for Na+ and Li+, which is ascribed to the highest formation energy and the lowest ion diffusion coefficient of the final potassiation product K3P, compared with Li3P and Na3P. As a result, restricting the formation of K3P by limiting the discharge voltage achieves a gravimetric capacity of 1300 mAh g−1 which retains at 600 mAh g−1 after 50 cycles at 0.25 A g−1. |
| 關鍵字 | alkali metal ion batteries; anode materials; black phosphorus; formation energy; ion diffusion coefficient |
| 語言 | en |
| ISSN | 1433-7851 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/123332 ) |