期刊論文
| 學年 | 107 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2018-08-20 |
| 作品名稱 | ALiZnP(2)O(7) (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20](14-) Anionic Skeleton |
| 作品名稱（其他語言） | |
| 著者 | Zhaohui Chen*, Yuan Fang, Wenyao Zhang, Wenqiang Chen, Xuefang Lu, Qun Jing*, and Ming-Hsien Lee |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Inorganic Chemistry 57(17), p.10568-10575 |
| 摘要 | Two new isotypic diphosphates, RbLiZnP2O7 (RLZP) and CsLiZnP2O7 (CLZP), have been synthesized by a high-temperature solid-phase method. They both crystallize in the Pnma space group (No. 62) and have similar crystal configurations. ALiZnP2O7 (A = Rb, Cs) consists of a [Li2Zn2P4O20]14– anionic skeleton, which is composed of Li/ZnO4 tetrahedral and diphosphate groups, and the Rb or Cs atoms are located in the large hole. In this paper, we discuss the structures of the title compounds and isonomic AA′ZnP2O7 (A = alkali metal); it is found that the ionic radii of the cations and bond angles have an effect on the symmetry of the compounds. By analysis, we found that the M/P values have some effect on the dimensionality of the anionic groups in phosphates containing P2O7 groups. Thermal and spectral analyses are carried out on the title compounds. Besides that mentioned above, we also studied the relationship between the electronic structures and optical properties by theoretical calculations. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/115579 ) |