期刊論文
| 學年 | 103 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2015-06-30 |
| 作品名稱 | Pressure Effect to the Molecular Structure of Ladder-type Poly(Para-phenylene) Revealed by Raman Spectroscopy |
| 作品名稱（其他語言） | |
| 著者 | Hsu, Che-hung; Yang, Shu-chun |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Journal of Applied Science and Engineering 18(2), pp.153-158 |
| 摘要 | Raman scattering spectra of blue light-emitted organic conjugated polymer, ladder-type poly para-phenylene with a phenyl ring in the side chain (Ph-LPPP), in the form of powder with trace-concentrations of metallic impurities under various pressures are measured. We find that Raman spectra shift to higher frequency with the increase of pressure, indicating a strong electron-phonon interaction. We also find that the shift rates of Raman peaks from the backbone of Ph-LPPP are different comparing to our early observations of Raman spectra of methyl substituted ladder-type poly (Me-LPPP). Planarization under pressure, therefore, electronic delocalization is observed, which is also discovered from the optical properties of Ph-LPPP. |
| 關鍵字 | Raman Scattering Spectrum;Hydrostatic Pressure;Conjugated Polymer;Electron-phonon Interaction |
| 語言 | en_US |
| ISSN | |
| 期刊性質 | 國內 |
| 收錄於 | EI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 是 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/106365 ) |