期刊論文
| 學年 | 90 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2002-04-01 |
| 作品名稱 | S-S Bond-activation of diorganyl disulfide by anionic [Mn(CO)5]-: crystal structures of [MnII(-SC5H4NO-)3]- and [(CO)3Mn(μ-SR)3Co(μ-SR)3Mn(CO)3]- (R = C6H4NHCOPh) |
| 作品名稱（其他語言） | |
| 著者 | Liaw, Wen-Feng; Hsieh, Chung-Hung; Peng, Shie-Ming; Lee, Gene-Hsiang |
| 單位 | 淡江大學化學學系 |
| 出版者 | Amsterdam: Elsevier BV |
| 著錄名稱、卷期、頁數 | Inorganica Chimica Acta 332(1), pp.153-159 |
| 摘要 | The S-S bond-activation of diorganyl disulfide by the anionic metal carbonyl fragment [Mn(CO)5]− gives rise to an extensive chemistry. Oxidative decarbonylation addition of 2,2′-dithiobis(pyridine-N-oxide) to [Mn(CO)5]−, followed by chelation and metal-center oxidation, led to the formation of [MnII(-SC5H4NO-)3]− (1). The effective magnetic moment in solid state by SQUID magnetometer was 5.88 μB for complex 1, which is consistent with the MnII having a high-spin d5 electronic configuration in an octahedral ligand field. The average Mn(II)-S, S-C and N-O bond lengths of 2.581(1), 1.692(4) and 1.326(4) Å, respectively, indicate that the negative charge of the bidentate 1-oxo-2-thiopyridinato [SC5H4NO]− ligand in complex 1 is mainly localized on the oxygen atom. The results are consistent with thiolate-donor [-SC5H4NO]− stabilization of the lower oxidation state of manganese (Mn(I)), while the O,S-chelating [-SC5H4NO-]− ligand enhances the stability of manganese in the higher oxidation state (Mn(II)). Activation of S-S bond as well as O-H bond of 2,2′-dithiosalicylic acid by [Mn(CO)5]− yielded [(CO)3Mn(μ-SC6H4-C(O)-O-)2Mn(CO)3]2− (4). Oxidative addition of bis(o-benzamidophenyl) disulfide to [Mn(CO)5]− resulted in the formation of cis-[Mn(CO)4(SR)2]− (R=C6H4NHCOPh) which was employed as a chelating metallo ligand to synthesize heterotrinuclear [(CO)3Mn(μ-SR)3Co(μ-SR)3Mn(CO)3]− (8) possessing a homoleptic hexathiolatocobalt(III) core. |
| 關鍵字 | Manganese(II)–thiolate; S-S Bond-activation; Heterotrinuclear Mn-Co-Mn-thiolate |
| 語言 | en |
| ISSN | 0020-1693 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | Liaw, Wen-Feng |
| 審稿制度 | 是 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97588 ) |