會議論文
| 學年 | 101 |
|---|---|
| 學期 | 1 |
| 發表日期 | 2012-08-19 |
| 作品名稱 | Moessbauer studies of model complexes for the H-cluster in [Fe-Fe]-hydrogenases: Electronic structure of mixed-valence complexes containing low-spin Fe(I) |
| 作品名稱（其他語言） | |
| 著者 | Popescu, Codrina V.; Stoian, Sebastian A.; Hsieh, Chung-Hung; Darensbourg, Marcetta Y.; Casuras, Andrea |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 244th ACS National Meeting & Exposition |
| 會議地點 | Philadelphia, PA, United States |
| 摘要 | Hydrogenases are enzymes that catalyze the reversible conversion of protons to mol. hydrogen. The active site of the [Fe-Fe]-hydrogenases (the H-cluster) can provide the required potential for this reaction using iron in low oxidn. states. Since it has been recognized that the H-cluster may contain low-spin Fe(I), monovalent iron has become a focus of bio-organometallic synthetic chem. In spite of its intriguing implication in hydrogenogenesis, the electronic structure of low-spin Fe(I) is unknown. The high asymmetry of the dinuclear site in the H-cluster stabilizes the elusive Fe(I)Fe(II... |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20120819~20120823 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 244th ACS National Meeting & Exposition, INOR-699 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97602 ) |