期刊論文
| 學年 | 99 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2011-05-01 |
| 作品名稱 | cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(l-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(l-SR)4[Fe(NO)2]3 |
| 作品名稱（其他語言） | |
| 著者 | Hsieh, Chung-Hung; Chupik, Rachel B.; Brothers, Scott M.; Hall, Michael B.; Darensbourg, Marcetta Y. |
| 單位 | 淡江大學化學學系 |
| 出版者 | Cambridge: R S C Publications |
| 著錄名稱、卷期、頁數 | Dalton Transactions 40(22), pp.6047-6053 |
| 摘要 | The reaction of Fe(CO)2(NO)2 and Ni(N2S2) (N2S2 = N,N′-Bis(2-mercaptoethyl)-1,4-diazacycloheptane) by a single CO replacement yields [Ni(N2S2)]Fe(NO)2(CO), while an excess of Fe(CO)2(NO)2 leads to triply bridging thiolate sulphurs in a cluster of core composition Ni2S4Fe3, lacking one Fe(NO)2 unit to complete the adamantane-like structure. This structural type was earlier identified in a CuICl aggregate of MII(N2S2) (MII = Ni, Cu), in which complete MII2S4CuI4 core structures were obtained as the major, and, in the case of CuII(N2S2), the incomplete CuII2S4CuI3 as a minor, product. The full Ni2S4Fe4 cluster has not yet been realized for Fe = Fe(NO)2. Computational analysis of the NiFe-heterobimetallic complex addresses structural issues including a ∠Ni–S–Fe of 90° in the bimetallic complex. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 1477-9226 1477-9234 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | Darensbourg, Marcetta Y. |
| 審稿制度 | 是 |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | 紙本 電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97546 ) |