期刊論文
| 學年 | 99 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2011-04-01 |
| 作品名稱 | Effect of Cr deficiency on physical properties of triangular-lattice antiferromagnets CuCr1−xO2 (0 ≦ x ≦ 0.10) |
| 作品名稱（其他語言） | |
| 著者 | Ling, D. C.; Chiang, C. W.; Wang, Y. F.; Lee Y. J.; Yeh, Ping-Hung |
| 單位 | 淡江大學物理學系 |
| 出版者 | College Park: American Institute of Physics |
| 著錄名稱、卷期、頁數 | Journal of Applied Physics 109(7), 07D908(3pages) |
| 摘要 | Structural, transport, and magnetoelectric (ME) properties of delafossite oxides CuCr1-xO2 with 0 <= x <= 0.10 were extensively investigated. The Rietveld refinement shows that the Cu-O bond length decreases with increasing Cr deficiency, indicative of the presence of a mixed valence state of Cu+/Cu2+ and an enhancement of the hybridization between Cu 3d and O 2p orbitals. As a result, it leads to a decrease of room-temperature resistivity by two orders of magnitude. The deduced effective moment for the Cr-deficient samples is larger than the one only taking into account the contribution from Cr3+ with S = 3/2. This demonstrates that Cu2+ is present in the Cr-deficient samples, giving rise to excess holes at the Cu site. Below TN(Cr) ∼ 24 K, the magnetocapacitance [[variant_greek_epsilon](H)-[variant_greek_epsilon](0)]/[variant_greek_epsilon](0) exhibits a distinct field dependence and deviates from the square of magnetization M2. These findings suggest that the ME coupling in CuCr1-xO2 with higher x is modulated by an increase of the spin fluctuations in the CrO2 triangular lattice through the interplay between charge and spin degrees of freedom. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0021-8979; 1089-7550 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | Ling, D. C. |
| 審稿制度 | |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | 紙本 電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/74844 ) |