期刊論文
| 學年 | 93 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2005-06-01 |
| 作品名稱 | Effect of Pr substitution on the electronic structure of (La1-xPrx)0.85Zr0.15MnO3 |
| 作品名稱（其他語言） | |
| 著者 | Jan, J.-C.; Chiou, J.-W.; Tsai, H.-M.; Bao, C.-W.; Hsu, B.-C.; Ling, D.-C.; Pong, W.-F.; Tsai, M.-H. |
| 單位 | 淡江大學物理學系 |
| 出版者 | Elsevier BV |
| 著錄名稱、卷期、頁數 | Journal of Electron Spectroscopy and Related Phenomena 144–147, pp.529–532 |
| 摘要 | We measured Mn L3,2-, K-, O K- and Pr M5,4-edges X-ray absorption near-edge structure (XANES) spectra of (La1−xPrx)0.85Zr0.15MnO3 (denoted as LPZMO) with x = 0, 0.05, 0.1, 0.15 and 0.2 to study their electronic structures and the effect of Pr substitution. An analysis of the Mn L3,2- and the K-edges spectra suggests that LPZMO is an electron-doped system. The average charge state of Mn ion is found to increase with the Pr substitution at low concentration as inferred from the enhancement of the unoccupied ↑spin eg subband in the Mn L3,2-edge XANES spectrum. The Mn L3,2-, O K- and Pr M5,4-edge XANES results revealed changes in the O 2p–Mn 3d and O 2p–Pr 4f hybridized states due to the substitution of La ions by smaller Pr ions. |
| 關鍵字 | Perovskite; Lanthanum-doped manganites; XANES |
| 語言 | en |
| ISSN | 0368-2048 1873-2526 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Pong, W.-F. |
| 審稿制度 | 是 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | 紙本 電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/72589 ) |