期刊論文
| 學年 | 99 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2011-05-17 |
| 作品名稱 | The dielectric properties of La(Mg0.5Ti0.5)O3 ceramics studied by Raman-scattering, infrared reflectivity spectroscopy, and first-principles calculations |
| 作品名稱（其他語言） | |
| 著者 | Liu, Hsiang-Lin; Hsueh, Hung-Chung; Lin, I-Nan; Yang, Ming-Ti; Lee, Wei-Chung; Chen, Yi-Chun; Chia, Chia-Ta; Cheng, Hsiu-Fung |
| 單位 | 淡江大學物理學系 |
| 出版者 | Bristol: Institute of Physics Publishing Ltd. |
| 著錄名稱、卷期、頁數 | Journal of Physics: Condensed Matter 23(22), 225901(8pages) |
| 摘要 | La(Mg0.5Ti0.5)O3 (LMT) ceramics were prepared by either the solid-state reaction (LMT)SS or the citric-acid chemical method (LMT)CA. A combination of Raman scattering, infrared reflectivity, and first-principles calculations was carried out to elucidate the correlation between lattice dynamics and the dielectric properties of these materials. Twelve Raman-active phonons are observed in both samples, displaying similar frequency positions. Interestingly, the Ag phonon (g11 mode) of (LMT)SS at about 717 cm − 1 involving the oxygen octahedron breathing vibrations demonstrates a narrower linewidth, suggesting its better crystallinity. Furthermore, an infrared-active u2 phonon band due to the vibrations of OI and OII layers, which possesses the largest oscillator strength, exhibits stronger intensity for (LMT)SS, as compared with those for (LMT)CA. Additionally, the Q × f values (the product of dielectric Q values and measurement frequency) of (LMT)SS estimated from either microwave cavity or infrared spectroscopic measurements are larger than those of (LMT)CA. These results indicate that the better coherence of lattice vibrations in (LMT)SS leads to its higher Q × f value, providing evidence for a strong connection between optical spectroscopic behavior and microwave dielectric characteristics in these materials. |
| 關鍵字 | |
| 語言 | en_US |
| ISSN | 0953-8984; 1361-648X |
| 期刊性質 | 國外 |
| 收錄於 | SCI EI |
| 產學合作 | |
| 通訊作者 | Liu, Hsiang-Lin; Hsueh, Hung-Chung |
| 審稿制度 | |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/55591 ) |