期刊論文
| 學年 | 91 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2003-06-01 |
| 作品名稱 | Effects of reducing structural symmetry on mesophase behaviour: the synthesis and characterization of the 2-alkoxy-6-[4-(4-alkoxyphenyl)buta-1,3-diynyl]naphthalenes |
| 作品名稱（其他語言） | |
| 著者 | 徐秀福; Hsu, Hsiu-fu; Lin, Wei-chung; Lai, Ying-hui; Lin, Shu-yu |
| 單位 | 淡江大學化學學系 |
| 出版者 | Taylor & Francis |
| 著錄名稱、卷期、頁數 | Liquid Crystals 30(8), pp.939-944 |
| 摘要 | Unsymmetrical 2-alkoxy-6-[4-(4-alkoxyphenyl)buta-1,3-diynyl]naphthalenes were synthesized and their mesomorphic properties studied. In addition to an increase the mesophase temperature range of 10°C, the melting temperatures are significantly lower while there is a less pronounced decrease in the clearing temperatures when compared with those of the symmetrical 1,4-bis(6-alkoxy-2-naphthyl)butadiynes. Further reducing the symmetry by introducing the two terminal chains of unequal length shows little effect on the mesogenic properties. Shortening the linker from a butadiynyne unit to an ethyne unit significantly reduces the overall mesophase and nematic temperature ranges but the smectic range markedly increases. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0267-8292 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24949 ) |